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The Best Electron Withdrawing Group Lower The Homo 2022. That's going to deactivate the ring towards future reactions. Electron withdrawing substituents alter the homo and lumo energy level and geometry of the molecule.
The carboxylic acid functional group is a strong electron withdrawing group and we see that the first pka is much lower than that of acetic acid. Conjugated compounds which absorb visible light do so when the difference in energy of the homo and lumo correspond to a frequency in the visible spectrum. The carboxylate anion is not nearly as strong.
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